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1,1,3,3-Tetramethylguanidine, 99%, Thermo Scientific Chemicals

Catalog No. AAA12314AC
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1,1,3,3-Tetramethylguanidine is employed as a polyurethane foam catalyst, as an accelerator for the syntheses of polysulfured rubber. It is also used as a strong base in the photochemical (couplers) and in the pharmaceutical (steroids) industries. It is essential for the preparation of alkyl nitriles from alkyl halides and 3'-alkylthymidines from 3'-nitrothymidines. It serves as an efficient and selective catalyst for the benzoylation of alcohols. It replaces the expensive bases 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1,3,3-Tetramethylguanidine is employed as a polyurethane foam catalyst, as an accelerator for the syntheses of polysulfured rubber. It is also used as a strong base in the photochemical (couplers) and in the pharmaceutical (steroids) industries. It is essential for the preparation of alkyl nitriles from alkyl halides and 3′-alkylthymidines from 3′-nitrothymidines. It serves as an efficient and selective catalyst for the benzoylation of alcohols. It replaces the expensive bases 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) in organic synthesis.

Solubility
Miscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents, mineral and organic acids, carbon dioxide. Keep away from sources of ignition.

Chemical Identifiers

CAS

80-70-6

Molecular Formula

C5H13N3

Molecular Weight (g/mol)

115.18

MDL Number

MFCD00008323

InChI Key

KYVBNYUBXIEUFW-UHFFFAOYSA-N

Synonym

tetramethylguanidine, n,n,n',n'-tetramethylguanidine, guanidine, n,n,n',n'-tetramethyl, tetramethyl guanidine, unii-vez101e7zu, 1,1,3,3-tetramethyl guanidine, n,n-1,1,3,3-tetramethylguanidine, vez101e7zu, 1,1,3,3-tetramethyl-guanidine, n,n,n',n'-tetramethyl-guanidine

PubChem CID

66460

IUPAC Name

1,1,3,3-tetramethylguanidine

SMILES

CN(C)C(=N)N(C)C

Specifications

Melting Point

<-30°C

Density

0.918

Boiling Point

162°C

Flash Point

60°C (140°F)

Refractive Index

1.469

Quantity

25 mL

UN Number

UN2920

Beilstein

969608

Sensitivity

Air Sensitive

Solubility Information

Miscible with water.

Formula Weight

115.18

Percent Purity

99%

Chemical Name or Material

1,1,3,3-Tetramethylguanidine

Hazard Category

H226-H302+H332-H314-H335

Hazard Statement

GHS H Statement
H314-H318-H226-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapor.
Harmful if swallowed.

Precautionary Statement

P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c

DOTInformation

Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUIDS, FLAMMABLE, N.O.S.

EINECSNumber

201-302-7

TSCA

Yes

Recommended Storage

Ambient temperatures; Store under Argon

RUO – Research Use Only

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