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1,3-Dithiane, 98%, Thermo Scientific Chemicals

Catalog No. AAA1050522
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1,3-Dithiane is used in umpolung reactions such as the Corey-Seebach reaction. It acts as a reagent for the deoxygenation of sulfoxides to their corresponding sulfides. Further, it is used as a protecting group for carbonyl compounds used in organic synthesis. It serves as a useful labeled synthon. In addition to this, it is used in the preparation of 2-ethyl-[1,3]dithiane.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,3-Dithiane is used in umpolung reactions such as the Corey-Seebach reaction. It acts as a reagent for the deoxygenation of sulfoxides to their corresponding sulfides. Further, it is used as a protecting group for carbonyl compounds used in organic synthesis. It serves as a useful labeled synthon. In addition to this, it is used in the preparation of 2-ethyl-[1,3]dithiane.

Solubility
Soluble in benzene, ether, chloroform and terahydrofuran. Slightly soluble in water.

Notes
Hygroscopic. Incompatible with strong bases and strong oxidizing agents.

Chemical Identifiers

CAS

505-23-7

Molecular Formula

C4H8S2

Molecular Weight (g/mol)

120.228

MDL Number

MFCD00006654

InChI Key

WQADWIOXOXRPLN-UHFFFAOYSA-N

Synonym

1,3-dithiacyclohexane, m-dithiane, dithiane-1,3, 1,3-dithian, dithiane-1,3 french, 1,3 dithiane, ccris 6777, m-dithiane, 8ci, 1,3 dithiocyclohexane, acmc-209knk

PubChem CID

10451

ChEBI

CHEBI:47845

IUPAC Name

1,3-dithiane

SMILES

C1CSCSC1

Specifications

Melting Point

52°C to 55°C

Boiling Point

207°C to 208°C

Flash Point

90°C (194°F)

Odor

Stench

Quantity

100 g

UN Number

UN3335

Beilstein

102534

Solubility Information

Soluble in benzene,ether,chloroform and terahydrofuran. Slightly soluble in water.

Formula Weight

120.24

Percent Purity

98%

Chemical Name or Material

1,3-Dithiane

DOTInformation

Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: AVIATION REGULATED SOLID, N.O.S.

EINECSNumber

208-006-7

RTECSNumber

JO5070000

TSCA

No

Recommended Storage

Ambient temperatures

RUO – Research Use Only

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