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2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF, Thermo Scientific Chemicals

Catalog No. AAH26739AD
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This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, be

Chemical Identifiers

CAS

193065-68-8

Molecular Formula

C5H10BrO2Zn-

Molecular Weight (g/mol)

247.417

MDL Number

MFCD00671976

InChI Key

APUPJTIEDQLKSC-UHFFFAOYSA-M

Synonym

2-ethoxycarbonyl ethylzinc bromide, 0.5m in thf

PubChem CID

131668631

IUPAC Name

ethyl propanoate;zinc;bromide

SMILES

CCC(=O)OCC.[Zn].[Br-]

Specifications

Density

0.972

Flash Point

−17°C (1°F)

Quantity

50 mL

UN Number

UN3399

Sensitivity

Air and moisture sensitive; May form a precipitate

Solubility Information

Reacts with water.

Formula Weight

246.42

Chemical Name or Material

2-(Ethoxycarbonyl)ethylzinc bromide

Hazard Category

H225-H260-H302-H314-H335-H336-H351

Hazard Statement

GHS H Statement
H225-H261-H314-H351-H335
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.

Precautionary Statement

P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

DOTInformation

Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

TSCA

No

Recommended Storage

Keep cold; Store under Argon

RUO – Research Use Only

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