9-Phenanthrylmagnesium bromide, 0.5M solution in THF, AcroSeal™, Thermo Scientific™

 

This Thermo Scientific brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Chemical Identifiers

CAS

71112-64-6, 109-99-9

Molecular Formula

C14H9BrMg

Molecular Weight (g/mol)

281.44

MDL Number

MFCD00672008

InChI Key

ACMUZKQPXSHTGB-UHFFFAOYSA-M

Synonym

9-phenanthrylmagnesium bromide, 9-phenanthryl-magnesiumbromid, magnesium,bromo-9-phenanthrenyl, magnesium,9h-phenanthren-9-ide,bromide, bromo phenanthren-9-yl magnesium, 9-phenanthrylmagnesium bromide, 0.5 m in thf, 9-phenanthrylmagnesium bromide, 0.25 m in 2-methf, 9-phenanthrylmagnesium bromide 0.5 m in tetrahydrofuran, grignard reagent

PubChem CID

12396678

IUPAC Name

magnesium;9H-phenanthren-9-ide;bromide

SMILES

Br[Mg]C1=CC2=C(C=CC=C2)C2=C1C=CC=C2

CAS Min %

11.91, 82.13

CAS Max %

17.87, 88.09

Color

Yellow to Brown

Density

0.9450g/mL

Flash Point

−17°C

Packaging

AcroSeal™ Glass Bottle

Quantity

50 mL

Specific Gravity

0.945

Solubility Information

Solubility in water: reacts.

Formula Weight

281.43

Physical Form

Solution

Chemical Name or Material

9-Phenanthrylmagnesium bromide

Hazard Category

GHS Signal Word: Danger

Hazard Statement

GHS H Statement
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.
Highly flammable liquid and vapor.
May form explosive peroxides.
Reacts violently with water.<br/

Precautionary Statement

GHS P Statement:
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Store in a dry place. Store in a closed container.
Keep container tightly closed.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/Bond container and receiving equipment.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

SDS

Hazard Category

GHS Signal Word: Danger

Hazard Statement

GHS H Statement
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.
Highly flammable liquid and vapor.
May form explosive peroxides.
Reacts violently with water.<br/

Precautionary Statement

GHS P Statement:
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Store in a dry place. Store in a closed container.
Keep container tightly closed.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/Bond container and receiving equipment.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

SDS

RUO – Research Use Only