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Allyltri-n-butyltin, 97%, Thermo Scientific Chemicals
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.
Solubility
Immiscible with water.
Notes
Air sensitive. Incompatible with strong oxidizing agents.
Specifications
Density
1.079
Boiling Point
100°C to 102°C (0.5 mmHg)
Flash Point
103°C (217°F)
Refractive Index
1.486
Quantity
25 g
UN Number
UN2788
Beilstein
3588340
Sensitivity
Air sensitive
Solubility Information
Immiscible with water.
IUPAC Name
tributyl(prop-2-en-1-yl)stannane
Hazard Category
H301-H312-H315-H319-H372
Hazard Statement
GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Precautionary Statement
P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c
DOTInformation
Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOTIN COMPOUNDS, LIQUID, N.O.S.
EINECSNumber
246-494-3
TSCA
No
Recommended Storage
Keep cold; Store under Argon
RUO – Research Use Only
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