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Bis(pentafluorophenyl)phenylphosphine, 97%, Thermo Scientific Chemicals

Catalog No. AAA1101401
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Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

Solubility
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.

Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.

Chemical Identifiers

CAS

5074-71-5

Molecular Formula

C18H5F10P

Molecular Weight (g/mol)

442.20

MDL Number

MFCD00000291

InChI Key

OYNXPGGNQMSMTR-UHFFFAOYSA-N

Synonym

bis pentafluorophenyl phenylphosphine, dftpp, decafluorotriphenylphosphine, bis perfluorophenyl phenyl phosphine, bis 2,3,4,5,6-pentafluorophenyl-phenylphosphane, phosphine,bis 2,3,4,5,6-pentafluorophenyl phenyl, bis 2,3,4,5,6-pentafluorophenyl phenyl phosphane, ultramark 443, bis pentafluorophenyl phenyl phosphite, bis pentafluorophenyl phenyl phosphine

PubChem CID

78757

IUPAC Name

bis(2,3,4,5,6-pentafluorophenyl)-phenylphosphane

SMILES

FC1=C(F)C(F)=C(P(C2=CC=CC=C2)C2=C(F)C(F)=C(F)C(F)=C2F)C(F)=C1F

Specifications

Melting Point

59°C to 64°C

Boiling Point

105°C (0.3 mmHg)

Flash Point

>110°C (230°F)

Quantity

0.25 g

Beilstein

6253897

Solubility Information

Soluble in chloroform,dichloromethane,tetrahydrofuran,benzene,toluene,ethanol,methanol,and supercritical carbon dioxide.

Formula Weight

442.2

Percent Purity

97%

Chemical Name or Material

Bis (pentafluorophenyl)phenylphosphine

Hazard Category

H302+H312+H332-H315-H319-H335

Hazard Statement

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

Precautionary Statement

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

EINECSNumber

225-780-1

TSCA

No

Recommended Storage

Ambient temperatures

RUO – Research Use Only

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