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Boron tribromide, 1M soln. in dichloromethane, Thermo Scientific Chemicals

Catalog No. AAL14880AE
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Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

Solubility
Miscible with ethanol and carbon tetrachloride.

Notes
Moisture sensitive. Reacts violently with water. Incompatible with alcohols, alkali metals, aluminum, sodium oxides and strong bases.

Chemical Identifiers

CAS

10294-33-4

Molecular Formula

BBr3

Molecular Weight (g/mol)

250.52

MDL Number

MFCD00011312

InChI Key

ILAHWRKJUDSMFH-UHFFFAOYSA-N

Synonym

boron tribromide, borane, tribromo, boron bromide, tribromoboron, hsdb 327, tribromoboran, boron tribrornide, boron tri bromide, boron tri-bromide

PubChem CID

25134

IUPAC Name

tribromoborane

SMILES

BrB(Br)Br

Specifications

Quantity

100 mL

UN Number

UN3390

Merck Index

14,1347

Solubility Information

Miscible with ethanol and carbon tetrachloride.

Formula Weight

250.52

Concentration or Composition (by Analyte or Components)

1M soln. in dichloromethane

Refractive Index

1.434

Sensitivity

Moisture sensitive

Density

1.467

Chemical Name or Material

Boron tribromide

Hazard Category

H300+H330-H314-H335-H336-H350-H373

Hazard Statement

GHS H Statement
H300-H330-H314-H351
Fatal if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Suspected of causing cancer.

Precautionary Statement

P201-P202-P260-P264b-P270-P271-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

DOTInformation

Transport Hazard Class: 6.1; Packing Group: I; Proper Shipping Name: TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.

EINECSNumber

233-657-9

TSCA

Yes

Recommended Storage

Ambient temperatures; Store under Nitrogen

RUO – Research Use Only

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