Bromopentacarbonylrhenium(I), 98%, Thermo Scientific Chemicals

 

This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

14220-21-4

Molecular Formula

C5BrO5Re

Molecular Weight (g/mol)

406.161

MDL Number

MFCD00013295

InChI Key

NWJBOTGGBYFKEJ-UHFFFAOYSA-M

Synonym

bromopentacarbonylrhenium, bromopentacarbonylrhenium i, bromorhenium; carbon monoxide, pentacarbonylbromorhenium, rebr co 5, bromopentacar-bonylrhenium, pentacarbonylrhenium bromide, rhenium i pentacarbonyl bromide, rhenium,bromopentacarbonyl-, oc-6-22-9ci

PubChem CID

6096983

IUPAC Name

bromorhenium;carbon monoxide

SMILES

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Br[Re]

Melting Point

∽90°C (Sublimation)

Color

White

Physical Form

Crystalline

Quantity

1 g

Linear Formula

Re(CO)₅Br

UN Number

UN3466

Solubility Information

Insoluble in water.

Formula Weight

406.16

Percent Purity

98%

Sensitivity

Air & Moisture Sensitive

Chemical Name or Material

Bromopentacarbonylrhenium(I)

Hazard Category

H302+H312+H332

Hazard Statement

GHS H Statement
H301-H331
Toxic if swallowed.
Toxic if inhaled.

Precautionary Statement

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

DOTInformation

Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: METAL CARBONYLS, SOLID, N.O.S.

EINECSNumber

238-084-8

TSCA

No

Recommended Storage

Ambient temperatures

SDS

Hazard Category

H302+H312+H332

Hazard Statement

GHS H Statement
H301-H331
Toxic if swallowed.
Toxic if inhaled.

Precautionary Statement

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

DOTInformation

Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: METAL CARBONYLS, SOLID, N.O.S.

EINECSNumber

238-084-8

TSCA

No

Recommended Storage

Ambient temperatures

SDS

RUO – Research Use Only