Promotional price valid on web orders only. Your contract pricing may differ. Interested in signing up for a dedicated account number?
Learn More

Thermo Scientific Chemicals Burgess Reagent, 96%

Catalog No. AAL2015503
Click to view available options
Quantity:

Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

Solubility
Soluble in organic solvents.

Notes
Store in cool place. Moisture sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS

29684-56-8

Molecular Formula

C8H18N2O4S

Molecular Weight (g/mol)

238.30

MDL Number

MFCD00077815

InChI Key

YSHOWEKUVWPFNR-UHFFFAOYSA-N

Synonym

methoxycarbonylsulfamoyl triethylammonium hydroxide, burgess reagent, carbomethoxysulfamoyltriethylammonium hydroxide, methoxycarbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulphamoyltriethylammonium hydroxide, methoxy-carbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulfa-moyl-triethylammonium hydroxide, methoxycarbonylsulphamoyl-triethylammonium hydroxide

PubChem CID

11032497

SMILES

CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC

Specifications

Melting Point

72°C to 82°C

Quantity

1 g

Beilstein

1432131

Sensitivity

Moisture sensitive

Solubility Information

Soluble in organic solvents.

IUPAC Name

(methoxycarbonyl)[(triethylazaniumyl)sulfonyl]azanide

Formula Weight

238.3

Percent Purity

96%

Chemical Name or Material

Burgess Reagent

Hazard Category

H315-H319-H335

Hazard Statement

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

Precautionary Statement

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

TSCA

No

Recommended Storage

Store at -20°C

RUO – Research Use Only

Product Title
Select an issue

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.