Carbonyldihydridotris(triphenylphosphine)ruthenium(II), White crystalline, 99%, Thermo Scientific Chemicals

Description

Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is used as Catalyst for conversion of 1,4-alkynediols into pyrroles, Catalyst for oxidation of primary alcohols to methyl esters, Catalyst for rearrangement of oximes to amides, Catalyst for C-C coupling via directed C-H activation, Catalyst for enyne cyclization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 25360-32-1
• Molecular Formula: C55H47OP3Ru
• Molecular Weight (g/mol): 917.97
• MDL Number: MFCD00015870 MFCD00015870
• InChI Key: MLIYPCQSOXNTLJ-UHFFFAOYSA-N
• PubChem CID: 53384314
• IUPAC Name: carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
• SMILES: [RuH2].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: 161°C to 163°C
• Color: White
• Assay Percent Range: 99%
• Quantity: 0.5 g
• Sensitivity: Light and moisture sensitive
• Solubility Information: Insoluble in water.
• Formula Weight: 917.97
• Physical Form: Crystals
• Chemical Name or Material: Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Safety and Handling

Hazard Category	H302+H312+H332
Hazard Statement	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.
Precautionary Statement	P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c
TSCA	No
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only