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Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%, Thermo Scientific Chemicals

Catalog No. AA1274901
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Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

12112-67-3

Molecular Formula

C16H24Cl2Ir2

Molecular Weight (g/mol)

671.70

MDL Number

MFCD00012414

InChI Key

ZFOUDQNHNLDNLD-MIXQCLKLSA-L

Synonym

chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+

PubChem CID

6436381

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride

SMILES

[Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point

190°C (decomposition)

Color

White

Odor

Odorless

Quantity

0.25 g

Solubility Information

Soluble in chloroform and toluene. Slightly soluble in acetone and alcohol. Insoluble in water.

Formula Weight

671.71

Physical Form

Crystalline Powder

Chemical Name or Material

Chloro(1, 5-cyclooctadiene)iridium(I) dimer

Hazard Category

H315-H319-H335

Precautionary Statement

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

EINECSNumber

235-170-7

TSCA

No

Recommended Storage

Ambient temperatures
SDS

RUO – Research Use Only

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