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Chlorobis(2-methoxyphenyl)phosphine, 98+%, Thermo Scientific Chemicals

Catalog No. AAH2589406
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Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

Chemical Identifiers

CAS

263369-88-6

Molecular Formula

C18H17ClO2P-

Molecular Weight (g/mol)

331.756

MDL Number

MFCD08064037

InChI Key

WVGQIZOJKMMSSK-UHFFFAOYSA-N

Synonym

bis 2-methoxyphenyl chlorphosphine, acmc-20alnz, phosphinous chloride,p,p-bis 2-methoxyphenyl

PubChem CID

57371085

SMILES

COC1=CC=CC=C1C2=C(P[Cl-]C=C2)C3=CC=CC=C3OC

Specifications

Melting Point

111°C to 114°C

Quantity

5 g

UN Number

UN3261

Sensitivity

Air and moisture sensitive

Solubility Information

Reacts with water.

Formula Weight

280.69

Percent Purity

≥98%

Chemical Name or Material

Chlorobis(2-methoxyphenyl)phosphine

Hazard Category

H314-H335

Hazard Statement

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

Precautionary Statement

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

DOTInformation

Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber

000-000-0

TSCA

No

Recommended Storage

Ambient temperatures; Store under Nitrogen

RUO – Research Use Only

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