Chlorobis(2-methoxyphenyl)phosphine, 98+%, Thermo Scientific Chemicals

Description

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

Specifications

Chemical Identifiers

• CAS: 263369-88-6
• Molecular Formula: C18H17ClO2P-
• Molecular Weight (g/mol): 331.756
• MDL Number: MFCD08064037
• InChI Key: WVGQIZOJKMMSSK-UHFFFAOYSA-N
• Synonym: bis 2-methoxyphenyl chlorphosphine, acmc-20alnz, phosphinous chloride,p,p-bis 2-methoxyphenyl
• PubChem CID: 57371085
• SMILES: COC1=CC=CC=C1C2=C(P[Cl-]C=C2)C3=CC=CC=C3OC

• Melting Point: 111°C to 114°C
• Quantity: 1 g
• UN Number: UN3261
• Sensitivity: Air and moisture sensitive
• Solubility Information: Reacts with water.
• Formula Weight: 280.69
• Percent Purity: ≥98%
• Chemical Name or Material: Chlorobis(2-methoxyphenyl)phosphine

Safety and Handling

Hazard Category	H314-H335
Hazard Statement	GHS H Statement H314-H318 Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statement	P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation	Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber	000-000-0
TSCA	No
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only