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Diisopropyl azodicarboxylate, 94%, Thermo Scientific Chemicals

Catalog No. AAL1038622
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Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

Solubility
Immiscible with water.

Notes
Store in cool place. Light sensitive. Incompatible with strong oxidizing agents, strong bases, alcohols and metallic salts. Decomposes violently at or above: 100 0C.

Chemical Identifiers

CAS

2446-83-5

Molecular Formula

C8H14N2O4

Molecular Weight (g/mol)

202.21

MDL Number

MFCD00008875

InChI Key

VVWRJUBEIPHGQF-KTKRTIGZSA-N

Synonym

z-n-propan-2-yloxy carbonyl imino propan-2-yloxy formamide

PubChem CID

56776520

IUPAC Name

propan-2-yl (NZ)-N-propan-2-yloxycarbonyliminocarbamate

SMILES

CC(C)OC(=O)N=NC(=O)OC(C)C

Specifications

Melting Point

3°C to 5°C

Density

1.027

Boiling Point

74°C to 75°C (0.3 mmHg)

Flash Point

160°C (320°F)

Odor

Pungent

Refractive Index

1.42

Quantity

100 g

UN Number

UN3082

Beilstein

1912326

Sensitivity

Light sensitive

Solubility Information

Immiscible with water.

Formula Weight

202.21

Percent Purity

94%

Chemical Name or Material

Diisopropyl azodicarboxylate

Hazard Category

H315-H319-H335-H373

Hazard Statement

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

Precautionary Statement

P260-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P314-P332+P313-P362-P501c

DOTInformation

Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

EINECSNumber

219-502-8

TSCA

No

Recommended Storage

Keep cold

RUO – Research Use Only

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