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Hexamethylphosphorous triamide, 97%, Thermo Scientific Chemicals

Catalog No. AAA1257130
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Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

Solubility
Miscible with water.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS

1608-26-0

Molecular Formula

C6H18N3P

Molecular Weight (g/mol)

163.21

MDL Number

MFCD00008301

InChI Key

XVDBWWRIXBMVJV-UHFFFAOYSA-N

Synonym

hexamethylphosphorous triamide, tris dimethylamino phosphine, hexametapil, phosphorous triamide, hexamethyl, hexamethyltriamidophosphite, hexamethyltriaminophosphine, phosphine, tris dimethylamino, bis dimethylamino phosphanyl dimethylamine, hmpt van, hexamethyl phosphorus triamide

PubChem CID

15355

IUPAC Name

N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine

SMILES

CN(C)P(N(C)C)N(C)C

Specifications

Melting Point

-44°C

Density

0.898

Boiling Point

162°C to 164°C

Flash Point

37°C (98°F)

Refractive Index

1.465

Quantity

250 g

UN Number

UN1993

Beilstein

906778

Sensitivity

Air sensitive; May form a precipitate

Solubility Information

Miscible with water.

Formula Weight

163.21

Percent Purity

97%

Chemical Name or Material

Hexamethylphosphorous triamide

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Hazard Category

H226-H315-H319-H335-H351

Hazard Statement

GHS H Statement
H340-H350-H226
May cause genetic defects.
May cause cancer.
Flammable liquid and vapour.

Precautionary Statement

P201-P202-P210-P233-P240-P243-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P308+P313-P332+P313-P362-P374-P380-P501c

DOTInformation

Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

EINECSNumber

216-534-4

RTECSNumber

TH3390000

TSCA

Yes

Recommended Storage

Ambient temperatures; Store under Nitrogen
SDS

RUO – Research Use Only

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