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Hydrogen fluoride pyridine complex, ca 70% HF, Thermo Scientific Chemicals

Catalog No. AAL1711714
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Hydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hydrogen fluoride pyridine complex is used to prepare beta-fluoroamines via reaction with amino alcohols. As a fluorinating agent, is involved in the fluorination of 2,2-diary-1,3-dithiolanes. It is associated with nitrosonium tetrafluorborate to prepare gem-difluorides by reacting with ketoximes. It is also used to convert secondary and tertiary alcohols into their respective alkyl fluorides.

Notes
Moisture sensitive. Store in cool place. Incompatible with strong bases, alkali metals, strong oxidizing agents, metals and strong acids. It reacts violently with water.

Chemical Identifiers

CAS

62778-11-4

Molecular Formula

C5H6FN

Molecular Weight (g/mol)

99.108

MDL Number

MFCD00012436

InChI Key

GRJJQCWNZGRKAU-UHFFFAOYSA-N

Synonym

pyridine hydrofluoride, hydrogen fluoride-pyridine, olah's reagent, pyridinium fluoride, hydrogen fluoride pyridine complex, hydrogen fluoride pyridine, hf-pyridine, pyridine, hydrofluoride 1:1, pyridinium poly hydrogen fluoride, hydrogen fluoride/pyridine

PubChem CID

64774

IUPAC Name

pyridine;hydrofluoride

SMILES

C1=CC=NC=C1.F

Specifications

Density

1.1

Boiling Point

50°C (1 mmHg)

Quantity

25 g

UN Number

UN1790

Beilstein

4750151

Sensitivity

Moisture sensitive

Merck Index

14,6821

Assay

≈70% HF

Chemical Name or Material

Hydrogen fluoride pyridine complex

Hazard Category

H300+H310+H330-H314-H335

Hazard Statement

GHS H Statement
H300-H310-H330-H314-H318
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.

Precautionary Statement

P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

DOTInformation

Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: HYDROFLUORIC ACID

TSCA

No

Recommended Storage

Keep cold; Store under Nitrogen

RUO – Research Use Only

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