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Isopentyl nitrite, 97%, stab. with 0.2% anhyd. sodium carbonate, Thermo Scientific Chemicals

Catalog No. AAL13909AP
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Isopentyl nitrite is used in the conversion of 2,6-disubstituted phenols to diphenoquinones and aminophenols to quinone diazides. It acts as an oxidant and nitrosating agent. It finds application in aromatic arylation, deamination of arylamines using tetrahydrofuran as a hydrogen donor. It is also useful for the preparation of benzyne using anthranilic acid. It is an antihypertensive and vasodilator to treat heart diseases such as angina and an antidote for cyanide poisoning. Further, it is used as a solvent and cleaning agent for a printed circuit board. In addition to this, it is considered to be a replacement for freon.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopentyl nitrite is used in the conversion of 2,6-disubstituted phenols to diphenoquinones and aminophenols to quinone diazides. It acts as an oxidant and nitrosating agent. It finds application in aromatic arylation, deamination of arylamines using tetrahydrofuran as a hydrogen donor. It is also useful for the preparation of benzyne using anthranilic acid. It is an antihypertensive and vasodilator to treat heart diseases such as angina and an antidote for cyanide poisoning. Further, it is used as a solvent and cleaning agent for a printed circuit board. In addition to this, it is considered to be a replacement for freon.

Solubility
Miscible with methanol, chloroform and ether. Slightly miscible with water.

Notes
Air, moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and alcohol.

Chemical Identifiers

CAS

110-46-3

Molecular Formula

C5H11NO2

Molecular Weight (g/mol)

117.15

MDL Number

MFCD00002057

InChI Key

OWFXIOWLTKNBAP-UHFFFAOYSA-N

Synonym

isoamyl nitrite, isopentyl nitrite, amilnitrite, vaporole, aspiral, nitrous acid, 3-methylbutyl ester, 3-methylbutanol nitrite, pentanoli nitris, nitrous acid, isopentyl ester, amyl nitrite i

PubChem CID

8053

ChEBI

CHEBI:2691

IUPAC Name

3-methylbutyl nitrite

SMILES

CC(C)CCON=O

Specifications

Density

0.875

Boiling Point

95°C to 100°C

Flash Point

−20°C (−4°F)

Odor

Sweet

Refractive Index

1.387

Quantity

500 mL

UN Number

UN1113

Beilstein

969510

Sensitivity

Air and light sensitive

Merck Index

14,5123

Solubility Information

Miscible with methanol,chloroform and ether. Slightly miscible with water.

Formula Weight

117.15

Percent Purity

97%

Chemical Name or Material

Isopentyl nitrite, stabilized with 0.2% anhyd. sodium carbonate

Hazard Category

H225-H302+H332

Hazard Statement

GHS H Statement
H225-H331-H302
Highly flammable liquid and vapor.
Toxic if inhaled.
Harmful if swallowed.

Precautionary Statement

P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P312-P330-P370+P378q-P501c

DOTInformation

Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: AMYL NITRITE

EINECSNumber

203-770-8

RTECSNumber

NT0187500

TSCA

Yes

Recommended Storage

Keep cold

RUO – Research Use Only

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