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Lithium dimethylamide, 96%, Thermo Scientific Chemicals

Catalog No. AA4414514
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It is used in the synthesis of some d0 organoimido complexes of the early transition metals and in meta rearrangement in the reaction of triphenyl-(p-bromophenyl)-silane.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

3585-33-9

Molecular Formula

C2H6LiN

Molecular Weight (g/mol)

51.017

MDL Number

MFCD00008295

InChI Key

YDGSUPBDGKOGQT-UHFFFAOYSA-N

Synonym

lithium dimethylamide, lithium dimethylazanide, linme2, acmc-20akms, dimethylamino lithium, lithiodimethylamine, lithium dimethylamide preparation, lithium 1+ dimethylazanide, lithium dimethylamide w/v in hexane

PubChem CID

5152226

IUPAC Name

lithium;dimethylazanide

SMILES

[Li+].C[N-]C

Specifications

Melting Point

(decomposition)

Color

White

Odor

Amine-like

Linear Formula

LiN(CH3)2

Quantity

25 g

UN Number

UN3393

Beilstein

3618233

Sensitivity

Air and moisture sensitive

Solubility Information

Reacts violently with water.

Formula Weight

51.02

Percent Purity

96%

Physical Form

Powder or Lumps

Chemical Name or Material

Lithium dimethylamide

Hazard Category

H250-H261-H314-H335

Hazard Statement

GHS H Statement
H250-H261-H314-H318
Catches fire spontaneously if exposed to air.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.

Precautionary Statement

P210-P222-P223-P231+P232-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c

DOTInformation

Transport Hazard Class: 4.2; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE

EINECSNumber

222-714-3

TSCA

No

Recommended Storage

Ambient temperatures; Store under Nitrogen

RUO – Research Use Only

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