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Lithium tert-butoxide, 99%, Thermo Scientific Chemicals

Catalog No. AA4636630
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Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of LixTiyOz thin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

1907-33-1

Molecular Formula

C4H9LiO

Molecular Weight (g/mol)

80.055

MDL Number

MFCD00050479

InChI Key

LZWQNOHZMQIFBX-UHFFFAOYSA-N

Synonym

lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate

PubChem CID

23664764

IUPAC Name

lithium;2-methylpropan-2-olate

SMILES

[Li+].CC(C)(C)[O-]

Specifications

Melting Point

∼150°C (decomposition)

Color

White to Cream

Odor

Odorless

Linear Formula

(CH3)3COLi

Quantity

250 g

UN Number

UN3206

Beilstein

3620018

Sensitivity

Air and moisture sensitive

Solubility Information

Soluble in toluene,hexane,tetrahydrofuran and methyl tert-butyl ether.

Formula Weight

80.06

Percent Purity

99%

Physical Form

Powder

Chemical Name or Material

Lithium tert-butoxide

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Hazard Category

H228-H302-H314

Hazard Statement

GHS H Statement
H251-H314-H302
Self-heating: may catch fire.
Causes severe skin burns and eye damage.
Harmful if swallowed.

Precautionary Statement

P210-P240-P241-P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

DOTInformation

Hazard Class: 4.1; Packaging Group: II

EINECSNumber

217-611-5

RTECSNumber

UB8520000

TSCA

Yes

Recommended Storage

Ambient temperatures; Store under Nitrogen
SDS

RUO – Research Use Only

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