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Mercury(II) trifluoromethanesulfonate, 98%, Thermo Scientific Chemicals

Catalog No. AA3930514
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Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

49540-00-3

Molecular Formula

C2F6HgO6S2

Molecular Weight (g/mol)

498.718

MDL Number

MFCD00144746

InChI Key

BPVYMDMPLCOQPJ-UHFFFAOYSA-L

Synonym

mercury ii trifluoromethanesulfonate, mercury triflate, mercury 2+ ditriflate, hg otf 2, ksc491a8p, mercury ii trifluoromethanesulphonate, mercury 2+ ; trifluoromethanesulfonate, mercury 2+ ion ditrifluoromethanesulfonate, mercury ii trifluoromethanesulfonate trace metals basis

PubChem CID

2775250

IUPAC Name

mercury(2+);trifluoromethanesulfonate

SMILES

C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Hg+2]

Specifications

Melting Point

>350°C

Color

White

Linear Formula

Hg(CF3SO3)2

Quantity

25 g

UN Number

UN2025

Sensitivity

Moisture sensitive

Solubility Information

It is soluble in H2O and CH3CN,fairly soluble in CH3NO2 and CH2Cl2,insoluble in hexane,ether,and toluene.

Formula Weight

498.72

Percent Purity

98%

Physical Form

Powder

Chemical Name or Material

Mercury(II) trifluoromethanesulfonate

Hazard Category

H300+H310+H330-H373

Hazard Statement

GHS H Statement
H300-H310-H330-H373
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
May cause damage to organs through prolonged or repeated exposure.

Precautionary Statement

P260-P262-P264b-P270-P271-P280-P284-P301+P310-P302+P350-P304+P340-P310-P314-P330-P361-P363-P501c

DOTInformation

Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: MERCURY COMPOUNDS, SOLID, N.O.S.

TSCA

No

Recommended Storage

Ambient temperatures

RUO – Research Use Only

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