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Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals

Catalog No. AAH2777222
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Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Chemical Identifiers

CAS

16695-14-0

Molecular Formula

C4H6O4

Molecular Weight (g/mol)

118.088

MDL Number

MFCD00667796

InChI Key

PBVZQAXFSQKDKK-UHFFFAOYSA-N

Synonym

methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate

PubChem CID

538366

IUPAC Name

3-methoxy-3-oxopropanoic acid

SMILES

COC(=O)CC(=O)O

Specifications

Density

1.128

Refractive Index

1.4295

Quantity

100 g

Formula Weight

118.09

Percent Purity

96%

Chemical Name or Material

Methyl hydrogen malonate

Hazard Category

H315-H319-H335

Hazard Statement

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

Precautionary Statement

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

TSCA

No

Recommended Storage

Keep cold

RUO – Research Use Only

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