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Phenyl chloroformate, 99%, Thermo Scientific Chemicals

Catalog No. AAA1261822
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Phenyl chloroformate is used in the synthesis of poly(2-(phenoxycarbonyloxy)ethyl methacrylate) and phenyl-(4-vinylphenyl) carbonate. It acts as a precursor of phenyl mixed anhydrides which are used in peptide coupling reactions. It serves as a dehydrating reagent for the conversion of primary amides to nitriles and an intermediate in the synthesis of pharmaceuticals and carbamates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl chloroformate is used in the synthesis of poly(2-(phenoxycarbonyloxy)ethyl methacrylate) and phenyl-(4-vinylphenyl) carbonate. It acts as a precursor of phenyl mixed anhydrides which are used in peptide coupling reactions. It serves as a dehydrating reagent for the conversion of primary amides to nitriles and an intermediate in the synthesis of pharmaceuticals and carbamates.

Solubility
Miscible with N,N-dimethylformamide.

Notes
Store in cool place. Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with bases, alcohols and amines. Hydrolyses in water.

Chemical Identifiers

CAS

1885-14-9

Molecular Formula

C7H5ClO2

Molecular Weight (g/mol)

156.57

MDL Number

MFCD00000637

InChI Key

AHWALFGBDFAJAI-UHFFFAOYSA-N

Synonym

phenyl chloroformate, chloroformic acid phenyl ester, phenyl chlorocarbonate, carbonochloridic acid, phenyl ester, phenoxycarbonyl chloride, formic acid, chloro-, phenyl ester, fenylester kyseliny chlormravenci, phenylchloroformate, unii-6tnd0d6d3y, 6tnd0d6d3y

PubChem CID

15891

IUPAC Name

phenyl carbonochloridate

SMILES

ClC(=O)OC1=CC=CC=C1

Specifications

Melting Point

-38°C

Density

1.246

Boiling Point

188°C to 189°C

Flash Point

76°C (169°F)

Refractive Index

1.511

Quantity

100 g

UN Number

UN2746

Beilstein

606778

Sensitivity

Moisture sensitive

Solubility Information

Miscible with N,N-dimethylformamide.

Formula Weight

156.57

Percent Purity

99%

Chemical Name or Material

Phenyl chloroformate

Hazard Category

H227-H302-H314-H317-H330-H335

Hazard Statement

GHS H Statement
H330-H314-H318-H227-H302-H317
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
Harmful if swallowed.
May cause an allergic skin reaction.

Precautionary Statement

P210-P235-P260-P264b-P270-P271-P272-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P501c

DOTInformation

Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: PHENYL CHLOROFORMATE

EINECSNumber

217-547-8

RTECSNumber

FG3850000

TSCA

Yes

Recommended Storage

Keep cold; Store under Nitrogen

RUO – Research Use Only

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