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Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals
Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
Color
Yellow to Brown
Density
1.14 g/mL
Odor
Ether-like
Quantity
100 mL
UN Number
UN3399
Sensitivity
Air, light, and moisture sensitive; May form a Precipitate
Solubility Information
Miscible with terahydrofuran.
IUPAC Name
bromo(phenyl)magnesium
Formula Weight
181.31
Concentration or Composition (by Analyte or Components)
3M in ether
Hazard Category
H224-H314-H335-H336
Hazard Statement
GHS H Statement
H224-H261-H314-H336
Extremely flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
Precautionary Statement
P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
DOTInformation
Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA
Yes
Recommended Storage
Ambient temperatures; Store under Argon
RUO – Research Use Only
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