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Poly(methylhydrosiloxane), Thermo Scientific Chemicals

Catalog No. AAL1456130
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Poly(methylhydrosiloxane) is used in the reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr. It is a safer alternative to triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. It is also used in greener amine synthesis by reductive amination as an alternative to borohydrides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

63148-57-2

Molecular Formula

(CH4OSi)n

MDL Number

MFCD00084478

InChI Key

QNWOFLWXQGHSRH-UHFFFAOYSA-N

Synonym

Methyl hydrogen polysiloxane; PMHS

SMILES

C[SiH](O[Si](C)(C)C)O[Si](C)(C)C

Specifications

Density

1.006

Solubility Information

Not miscible or difficult to mix in water.

Quantity

250 g

Formula Weight

ca 1900

Flash Point

204°C (399°F)

Refractive Index

1.398

Chemical Name or Material

Poly(methylhydrosiloxane)

TSCA

Yes

Recommended Storage

Ambient temperatures

RUO – Research Use Only

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