Tebbe reagent, 0.5M solution in toluene, AcroSeal™, Thermo Scientific Chemicals

 

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

For C-C Bond Formation (Olefination), Lewis acid

Chemical Identifiers

CAS

67719-69-1, 108-88-3

Molecular Formula

C₁₃H₁₈AlClTi

MDL Number

MFCD00151575

Synonym

Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium

Color

Purple to Red

Density

0.9270g/mL

Flash Point

4°C

Packaging

AcroSeal™ Glass bottle

Quantity

100 mL

Specific Gravity

0.927

Merck Index

15, 9228

Formula Weight

284.62

Physical Form

Solution

Chemical Name or Material

Tebbe reagent, 0.5M solution in toluene

Hazard Category

Danger

Hazard Statement

GHS H Statement
Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Highly flammable liquid and vapor.

Precautionary Statement

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment.

SDS

Hazard Category

Danger

Hazard Statement

GHS H Statement
Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Highly flammable liquid and vapor.

Precautionary Statement

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment.

SDS

RUO – Research Use Only