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tert-Butyl nitrite, tech. 90%, Thermo Scientific Chemicals

Catalog No. AAL1613522
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tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Solubility
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.

Notes
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.

Chemical Identifiers

CAS

540-80-7

Molecular Formula

C4H9NO2

Molecular Weight (g/mol)

103.121

MDL Number

MFCD00002055

InChI Key

IOGXOCVLYRDXLW-UHFFFAOYSA-N

Synonym

t-butyl nitrite, 1,1-dimethylethyl nitrite, tert-butylnitrite, nitrous acid, 1,1-dimethylethyl ester, unii-4780h7u8lu, ccris 2098, alpha,alpha-dimethylethyl nitrite, nitrous acid, t-butyl ester, 2-methyl-2-propylnitrit, ch3 3cono

PubChem CID

10906

IUPAC Name

tert-butyl nitrite

SMILES

CC(C)(C)ON=O

Specifications

Density

0.867

Boiling Point

61°C to 63°C

Flash Point

−23°C (−9°F)

Odor

Sweet

Refractive Index

1.369

Quantity

100 g

UN Number

UN2351

Beilstein

1209339

Merck Index

14,1583

Solubility Information

Miscible with diethyl ether,chloroform,alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.

Formula Weight

103.12

Percent Purity

90%

Grade

Technical

Chemical Name or Material

tert-Butyl nitrite

Hazard Category

H225-H302+H332

Hazard Statement

GHS H Statement
H225-H302-H332
Highly flammable liquid and vapor.
Harmful if swallowed.
Harmful if inhaled.

Precautionary Statement

P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P312-P330-P370+P378q-P501c

DOTInformation

Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: BUTYL NITRITES

EINECSNumber

208-757-0

RTECSNumber

RA0802000

TSCA

No

Recommended Storage

Keep cold

RUO – Research Use Only

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