trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min, Thermo Scientific Chemicals

Hydrogenation, hydrosilation, carbonylation, oxidation, and C-C bond formation

As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS

13965-03-2

Molecular Formula

C36H30Cl2P2Pd

Molecular Weight (g/mol)

701.90

MDL Number

MFCD00009593

InChI Key

YNHIGQDRGKUECZ-UHFFFAOYSA-L

Synonym

bis triphenylphosphine palladium ii dichloride, bis triphenylphosphine palladium ii chloride, dichlorobis triphenylphosphine palladium, bis triphenylphosphine palladium chloride, bis triphenylphosphine palladiuml ii dichloride, palladium 2+ ; triphenylphosphane; dichloride, trans-dichlorobis triphenylphosphine palladium ii 1g

PubChem CID

131664180

IUPAC Name

ethane;methane;palladium(2+);triphenylphosphane;dichloride

SMILES

[Cl-].[Cl-].[Pd++].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Melting Point

∼310°C (decomposition)

Color

Yellow

Odor

Odorless

Linear Formula

PdCl₂[P(C₆H₅)₃]₂

Quantity

5 g

Sensitivity

Hygroscopic

Solubility Information

Insoluble in water. Soluble in benzene,and toluene.

Formula Weight

701.91

Concentration or Composition (by Analyte or Components)

Pd 14.0% min.

Physical Form

Crystalline

Chemical Name or Material

trans-Dichlorobis(triphenylphosphine)palladium(II)

EINECSNumber

237-744-2

RTECSNumber

RT3578000

TSCA

No

Recommended Storage

Ambient temperatures

SDS

EINECSNumber

237-744-2

RTECSNumber

RT3578000

TSCA

No

Recommended Storage

Ambient temperatures

SDS

RUO – Research Use Only